コーヒーを飲みながら話しましょう。

coffee

indicates direct object of action; indicates subject of causative expression; indicates an area traversed; indicates time (period) over which action takes place; indicates point of departure or separation of action; indicates object of desire, like, hate, etc.

to drink; to gulp; to swallow; to take (medicine); to smoke (tobacco); to engulf; to overwhelm; to keep down; to suppress; to accept (e.g. demand, condition); to make light of; to conceal

while; during; as; while; although; though; despite; in spite of; notwithstanding; all; both; as (e.g. "as always", "as long ago"); in (e.g. "in tears")

to talk; to speak; to converse; to chat; to tell; to explain; to narrate; to mention; to describe; to discuss; to speak (a language)